i have a 70 - 200 with a 1.4x converter and they work very well together givin nice sharp images but maximum focal length is 280mm
i believe the 2x converter produces softer images but would give you the 400mm you are looking for
to be honest i would go for both
the 100 - 400 for the wildlife ( plus 1.4 converter if you so desire )
and the 70 - 200 for your portraits
be extravagant you can never have too many lenses
there's a point to this...
people tend to buy long lenses for their reach the shorter end of the lens is not as important as it's longest reach and where wildlife is concerned you never have enough reach
a 300mm prime even with a 1.4 converter attached will give superior results than an equivilent zoom ( something worth considering )
the 100 - 400 will be my next lens purchase to replace my sigma 170 - 500 which goes soft beyond 400mm anyway
i allready have the 24 -105 f4 L is which makes a great carry around lens i think this lens is more suited for the family portrate jobs and the 70 - 200mm with or without converter for wildlife etc..
if you consider the 100 - 400 L lens try before you buy it is known that some can be quite soft make sure the one you purchase isn't