Having had a chance now to look at the images, and the exif, I see you've used a slow shutter to expose for the background, and used the flash to stop the motion in the subject. This is called 'dragging the shutter' did you do it deliberately, or is it a happy accident?
The background was quite well lit which has allowed you to capture it, but there are a few when the subject isn't back lit and the background is black
http://www.flickr.com/photos/f18/417...7622851778463/
As you have a 5D MkII Canons DPP has a few tools built into it which should give an automatic 'best settings' for each setting of the camera, you should give this a try (you did shoot in RAW didn't you?).