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By all means try it but I don't think the 2nd curtain is what you need as I bet your firing at fast shutters. I assume your trying to get either a reflection in a drop or no flash shots in a plop. I would say if your using on-camera flash then turning down the flash exposure would help more then 2nd curtain. 2nd curtain is used typically with slow shutters. However you never know so trying it would be a good idea.
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