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Thanks for your info. You set me on the right path.
I've figured it out. To switch the Nissin Di866 to Slave mode, you need to navigate to the M/Av menu. Once in there, PRESS AND HOLD the SET button for TWO SECONDS. Another menu (which isn't in the manual) will appear and allow you to switch the Slave mode between SD (Slave Digital) or SF (Slave Film). For the pop-up flash to trigger the DI866 in remote, the Slave mode needs to be set to SD. It isn't by default!
All the best
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