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Provided it's not physically connected to the camera then I don't see why not.
I actually purchased (for the grand price of £2.75) a very small flash slave unit which is great. I set the slave flash on manual (an old Sunpack - which you can pick up fairly cheaply on e-bay or in a second hand shop), adjust it's power, move it where I want it. I set my on-camera flash to minimum power (easy on the D90), set flash to commander mode, and my SB-600 to wireless and position that where I want it and then flash away!
Cheap and cheerful - but works
Phil
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