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It's a while since I used PS5 but try this.
Go to Image Size (Alt-Ctrl-I)
Set the resolution to 300 dpi and make sure the 'Resample Image' box is NOT ticked.
Now look at your image again at 100%. Does it look any sharper?
I don't know the pixel dimensions of your camera's images but I'm guessing your camera is setting the dpi to 72 and that means (printed at that resolution) an image size of 53" X 28". If you look at the image at 100% you are looking at individual pixels and they won't look sharp.
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